On the reaction of methyl dichlorophosphine with acrylamide

Autor: Khairullin, V. K., Kondrat'eva, R. M., Pudovik, A. N.
Zdroj: Russian Chemical Bulletin; September 1967, Vol. 16 Issue: 9 p2019-2021, 3p
Abstrakt: 1.The following compounds are formed by the reaction of methyl dichlorophosphine with acrylamide: methyl-ß-cyanoethylphosphonyl chloride (36.6%),ß-chloropropionitrile (16.2%) and methyl-ß-cyanoettylphosphonic acid (3.4%).2.The reaction of methyl-ß-cyanoethylphosphonyl chloride with water (2:1) gave methyl-ß-cyanoethylphosphonic acid anhydride.3.By reacting methyl-ß-cyanoethylphosphonyl chloride with alcohols and diethylamine, we have obtained a number of esters and the diethylamide of methyl-ß-cyanoethylphosphonic acid.
Databáze: Supplemental Index