The hydrochlorination reaction of β-silicon-containing vinyl ethers

Autor: Shostakovskii, M. F., Komarov, N. V., Tsykhanskaya, I. I., Vlasova, N. N.
Zdroj: Russian Chemical Bulletin; April 1968, Vol. 17 Issue: 4 p877-879, 3p
Abstrakt: 1.The hydrochlorination of ß-silicon-containing vinyl ethers was investigated and it was shown that at a temperature below 30°, the reaction proceeds with the formation of ß -silicon-containing a-chloroethyl ethers.2.In contrast to the sulfur analogues, the ß-silicon-containing vinyl sulfides, at a temperature above -15° and an excess of hydrogen chloride, the formation of ß -silicon-containing a-chloro ethers is complicated by their cleavage at the Si-C bond. A reaction scheme is presented.
Databáze: Supplemental Index