Thermal polymerization of p-allylphenyl phenyl ether

Autor: Rudenko, M. G., Yaroshevskaya, S. M.
Zdroj: Russian Chemical Bulletin; May 1967, Vol. 16 Issue: 5 p1088-1091, 4p
Abstrakt: Conclusions 1.The thermal polymerization of p-allylphenyl phenyl ether was studied.2.In thermal polymerization at 250° 1,6-bis-p-phenoxyphenyl-1-hexene is obtained in two isomeric forms: a solid dimer — the transform — and a liquid dimer — the cis form containing 25–30% of the trans isomer. The structure of the dimers was established by investigation of their oxidation and their molecular spectra.3.The following previously undescribed compounds were synthesized; p-allylphenyl phenyl ether, p-3-bromophenylphenyl phenyl ether, 3-p-phenoxyphenyl-1-propanol, and 4,4'-diphenoxybiphenyl.
Databáze: Supplemental Index