| Autor: |
Shuikin, N. I., Lebedev, B. L. |
| Zdroj: |
Russian Chemical Bulletin; March 1967, Vol. 16 Issue: 3 p615-618, 4p |
| Abstrakt: |
1.The alkylation of tetrahydrofuran with alkenes and unsaturated ethers in presence of di-t-butyl peroxide was investigated. Alkylation goes at the 2-carbon atom of tetrahydrofuran, and alkenes and unsaturated ethers add through their terminal unsaturated carbon atom.2.The effect of the proportions of the components, the length of the carbon chain of the alkene, and other factors on the yield of the monoderivative was studied. With diminution in the concentration of 1-hexene in the reaction mixture from 33 to 3.3%, the yield of hexyltetrahydrofuran rises from 13.2 to 79.2%.3.Alkylation in presence of the peroxide is accompanied by the isomerization of the alkyltetrahydrofuran into the corresponding aliphatic ketone. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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