Autor: |
Mursakulov, I. G., Semenovskii, A. V., Smit, V. A. |
Zdroj: |
Russian Chemical Bulletin; February 1967, Vol. 16 Issue: 2 p362-367, 6p |
Abstrakt: |
1.Structural and steric orientation in the cyclization of 3-methylgeranylacetone (trans-6,7) was studied. The protonation of the terminal (2,3) double bond goes with a high degree of stereospecificity.2.The cyclization of cis-6,7-3-methylgeranylacetone goes with some loss (to the extent of 30%) of stereospecifity in the formation of the bicyclic system. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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