| Autor: |
Gol'dberg, V. M., Obukhova, L. K. |
| Zdroj: |
Russian Chemical Bulletin; July 1967, Vol. 16 Issue: 7 p1376-1380, 5p |
| Abstrakt: |
1.The kinetics of the reduction of trivalent manganese by a carboxylic acid was studied.2.The hypothesis of an ionic character of the reaction was confirmed by qualitative experiments and by agreement of the calculation of the kinetic scheme with the experimental data.3.The rate constants of the following reactions at 120° were found: dissociation of the acid into ions k1=3·10-5 sec-1, association of the anion and cation of the acid k2=3 liters/mole· sec, reaction of the anion of the acid with trivalent manganese k3=2 liters/mole· sec. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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