Structure of albonoursin and its natural analog

Autor: Khokhlov, A. S., Lokshin, G. B., Vul'fson, N. S., Zaretskii, V. I.
Zdroj: Russian Chemical Bulletin; July 1966, Vol. 15 Issue: 7 p1146-1152, 7p
Abstrakt: 1.Albonoursin is 3-benzylidene-6-isobutylidene-2,5-piperazinedione.2.A natural analog of albonoursin was isolated from the mycelia ofActinomyces albus var. fungatus andA. noursei, a number of its chemical properties were studied, and it was shown that it is 3,6-dibenzylidene-2,5-piperazinedione.3.The cleavage of 3,6-dibenzylidene-2,5-piperazinediones and albonoursin under the action of electron impact was studied, and a general scheme for the fragmentation of these compounds was established.4.The halogenation of albonoursin and its analog was studied, and it was shown that substitution in the methine groups occurs.
Databáze: Supplemental Index