| Autor: |
Vdovin, V. M., Nametkin, N. S., Pushchevaya, K. S., Topchiev, A. V. |
| Zdroj: |
Russian Chemical Bulletin; February 1963, Vol. 12 Issue: 2 p250-255, 6p |
| Abstrakt: |
1.1-(Chloromethyl)-1-methylsilacyclopentane was synthesized from dichloro(chloromethyl)methylsilane and tetramethylene bis(magnesium bromide).2.1-(Chloromethyl)-1-methylsilacyclopentane is active at the chlorine in nucieophilic-substitution reactions and can serve as the starting substance for the synthesis of silacyclopentanes having functional groups in the methyl group.3.Under the action of aluminum chloride 1-(chloromethyl)-1-methylsilacyclopentane is converted into 1-chloro-1-memylsilacyclohexane. This is the first recorded case of the enlargement of a heterocycle containing a silicon atom in the ring. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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