Polymerization of monoallyl silicon derivatives in presence of the catalyst system (i-C4H9)3Al+TiCl4

Autor: Topchiev, A. V., Nametkin, N. S., Hsiao-p'ei, Ch'iu, Durgar'yan, S. G., Zav'yalov, V. I.
Zdroj: Russian Chemical Bulletin; February 1963, Vol. 12 Issue: 2 p244-249, 6p
Abstrakt: 1.By the polymerization of allyltrimethylsilane and of allyldimethylphenylsilane in presence of the complex catalyst (i-C4H9)3 Al+TiCl4, high-molecular crystalline polyallyltrimethylsilane and polyallyldimethylphenylsilane can be obtained.2.A study was made of the effect of the relative amounts of triisobutylaluminum and titanium tetrachloride on the yield and properties of the solid polymers.
Databáze: Supplemental Index