Alkylation of phenols with compounds with mixed functions

Autor: Shuikin, N. I., Viktorova, E. A., Pokrovskaya, I. E., Malysheva, T. G.
Zdroj: Russian Chemical Bulletin; October 1961, Vol. 10 Issue: 10 p1725-1728, 4p
Abstrakt: 1.An investigation was made of the alkenylation of m- and p-cresols with 4-penten-1-ol in presence of phosphoric acid.2.As a result of the alkenylation the corresponding (methylbutenyl) cresols and their cyclization products (chromanes) were obtained.3.The alkenylation of cresols with 4-penten-1-ol proceeds by a mechanism that differs from that of alkenylation with allyl alcohol. 1,4-Pentadiene forms an intermediate product in the reaction.
Databáze: Supplemental Index