Reaction of tetraalkyl- 1,3-Bis-ω-chloroalkyldisiloxanes with ethylamine

Autor: Petrov, A. D., Vdovin, V. M., Pushchevaya, K. S.
Zdroj: Russian Chemical Bulletin; January 1960, Vol. 9 Issue: 1 p135-137, 3p
Abstrakt: Summary 1.Reaction between 1,3-bischloromethyltetramethyldisiloxane and ethylamine proceeds at room temperature with formation of the cyclic monoamine 4-ethyl-2,2,6,6-tetramethyl-1-oxa-4-aza-2,6-disilacyclohexane.2.Tetraalkyl-1,3-bis-3-chloropropyldisiloxanes do not react with ethylamine at room temperature, but at elevated temperatures reaction occurs with formation of a linear diamine.
Databáze: Supplemental Index