| Autor: |
Yakhontov, L. N., Krasnokutskaya, D. M., Akalaev, A. N., Palant, I. N., Vainshtein, Yu. I. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; June 1971, Vol. 7 Issue: 6 p736-740, 5p |
| Abstrakt: |
In addition to normal nucleophilic substitution, redox processes to form dehalogenation products of 7-azaindoline and the corresponding oxidized compounds — 6-amino-7-azaindole derivatives — occur during the reactions of various primary and secondary amines with 6-chloro-7-azaindolines. The quantitative ratios of the products of nucleophilic substitution and the redox reaction depend mainly on the nucleophilicity of the attacking amine and, by selecting the amine component of the reaction, one can accomplish either predominantly nucleophilic substitution or direct the process primarily along the path of the redox reaction. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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