Formylation and vinylformylation of 2,3-cycloalkenobenzopyrylium salts
Autor: | Shelepin, N. E., Loseva, N. S., Nivorozhkin, L. E., Minkin, V. I. |
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Zdroj: | Chemistry of Heterocyclic Compounds; June 1971, Vol. 7 Issue: 6 p684-686, 3p |
Abstrakt: | Heating of 2,3-cycloalkenobenzopyrylium salts in acetic anhydride with excess formylating agent (dimethylformamide, formanilide, N-formylmorpholine, and N-phenyl-N-methyl-aminoacrolein) gives monoiminium salts, the hydrolysis of which yields aldehydes or, in the presence of hydrosulfide, thioaldehydes. On treatment with the Vilsmeier complex, 1-methylquinaldinium salts give diiminium salts, which are hydrolyzed to the corresponding aldehydes. |
Databáze: | Supplemental Index |
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