Carbolines

Autor: Kuchkova, K. I., Semenov, A. A., Terent'eva, I. V.
Zdroj: Chemistry of Heterocyclic Compounds; February 1970, Vol. 6 Issue: 2 p182-186, 5p
Abstrakt: 4-Substituted 3, 4-dihydro-?-carbolines (X–XVI) were obtained by the Beckman rearrangement of oximes of ?-(indolyl-3')ketones (I–IV, IX) under the action of phosphorus pentachloride in nitrobenzene. 3, 4-Dihydro-?-carbolines were converted into ?-carbolines (XV–XVII) on heating with Brown's palladium catalyst in ethylene glycol. Oximes containing the aryl group react on treatment with p-toluene sulfochloride in pyridine with the formation of the arilides of ?-(indolyl-3')propionic acids.
Databáze: Supplemental Index