Autor: |
Mel'nikova, T. V., Kost, A. N., Sagitullin, R. S., Borisov, N. N. |
Zdroj: |
Chemistry of Heterocyclic Compounds; September 1973, Vol. 9 Issue: 9 p1154-1159, 6p |
Abstrakt: |
The reaction of 2-aminoindole with a,ß-unsaturated aldehydes and ketones leads to a-carbolines, the ß-carbon atom of the oxo compound attacking C3 of the indole. In a number of cases, reactions with bifunctional derivatives take place with the cleavage of a carbon-carbon bond and the formation of the pentacyclic system of indolo[2,3-b]-a-carboline. The same substances are obtained from 2-amino-3-(arylmethylene)indoles and 3-(arylmethylene)-oxindoles. The replacement of one molecule of 2-aminoindole by other acceptors did not lead to the formation of unsymmetrical structures. |
Databáze: |
Supplemental Index |
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