| Autor: |
Taits, S. Z., Kalinovskii, O. A., Bogdanov, V. S., Gol'dfarb, Y. L. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; November 1970, Vol. 6 Issue: 11 p1367-1372, 6p |
| Abstrakt: |
A mixture of isomers corresponding to closing of the ring at the 3 and 4 positions of the thiophene ring is formed during intramolecular acylation of 12-(5-methyl-2-thienyl)-lauryl chloride in a homogeneous medium; the reaction proceeds primarily to favor the formation of the isomer with the larger ring (80%). A method for the synthesis of macrocyclic a-alkylcycloalkanones by reductive desulfurization of the corresponding bicyclic ketones, which contain thiophene rings, was developed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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