Influence of π-electronic charges on the chemical shifts of the meso-protons in β-ethoxycarbonyl-substituted porphyrins

Autor: Mamaev, V. M., Zenin, S. V., Ponomarev, G. V., Evstigneeva, R. P.
Zdroj: Chemistry of Heterocyclic Compounds; September 1971, Vol. 4 Issue: 5 p685-686, 2p
Abstrakt: A calculation has been made of the influence of the electric field of p-electronic charges on the chemical shifts of the meso-protons in ß-ethoxycarbonyl-substituted porphyrins. A comparison of the calculated and experimental figures shows that the change in the chemical shifts taking place with the introduction of ethoxycarbonyl substituents into the ß-position is due mainly to the changes in the p-electronic charges.
Databáze: Supplemental Index