Structure of the condensation product of benzalaniline with N,N-dimethylamide of dichloroacetic acid under darzens reaction conditions

Autor: Mamedov, V. A., Litvinov, I. A., Sibgatullina, F. G., Kataeva, O. N., Nuretdinov, I. A., Naumov, V. A.
Zdroj: Chemistry of Heterocyclic Compounds; February 1994, Vol. 30 Issue: 2 p169-172, 4p
Abstrakt: Condensation of benzalaniline with N,N-dimethylamide of dichloroacetic acid under Darzens reaction conditions was used to obtain r-1, t-3-diphenyl-c-2-chloro-2-(NN-dimethylcarbamoyl)aziridine. The structure was established by x-ray diffraction analysis. Stabilization of the position of the substituents at the atoms of the aziridine ring by the hyperconjugation interaction of the unshared electron pair of the nitrogen atom with the antibonding orbital of the C-CI bond is discussed.
Databáze: Supplemental Index
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