Researches on benzodiazines

Autor: Postovskii, I. Ya., Vereshchagina, N. N., Mertsalov, S. L.
Zdroj: Chemistry of Heterocyclic Compounds; January 1966, Vol. 2 Issue: 1 p94-97, 4p
Abstrakt: 2-R-Quinazolones have been synthesized (R=Me, Ph,?-pyridyl,a-furyl), and subsequently the 4-chlorides and the corresponding 2-R-4-hydrazinoquinazolines were obtained. By the reaction of orthoformic ester and nitric acid on the hydrazines, 5-R- [3, 4-c]-s-triazoloquinazolines and 5-R- [1, 5-c] tetrazoloquinazolines were prepared, respectively. The compounds in which R=Me differ considerably from compounds with other groups, both in color and stability of intermediate reaction products. 5-R- [1, 5-c] tetrazoloquinazolines are hydrolyzed by HCl into quinazol-4-ones.
Databáze: Supplemental Index