Reactions of furan aldehydes 4. Oxidation-reduction reactions of furfural with monohydric alcohols
Autor: | Shapiro, Yu. M. |
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Zdroj: | Chemistry of Heterocyclic Compounds; January 1993, Vol. 29 Issue: 1 p20-22, 3p |
Abstrakt: | Furfural oxidizes aliphatic and alicyclic alcohols at 70–100°C under the action of sodium alcoholate to aldehydes and ketones, and then participates in a crotonate condensation. At 0–10°C the alcohol is not oxidized but the adduct with alkoxide ion is oxidized to form an alkyl furoate. |
Databáze: | Supplemental Index |
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