Synthesis and stereochemistry of (−)-(10s)-6,10-dimethyl-6-aza-δ1,9-octahydroquinoline

Autor: Gaidarova, E. L., Rosher, K., Aliev, A. É., Grishina, G. V.
Zdroj: Chemistry of Heterocyclic Compounds; October 1992, Vol. 28 Issue: 10 p1175-1178, 4p
Abstrakt: Enantiomericalfy pure (-)-(10S)-6,10-dimethyl-6-am-?1,9-octahydroquinoline, which has been obtained from optically pure (3S)-1,3-dimethyl-3-(2-cyanoethyl)piperid-4-one, is a chiral intermediate for the preparation of novel biologically active compounds and an analog of piperidine and decahydroquinoline alkaloids. The chiroptical properties of the synthesized 6-azaoctahydroquinoline are examined.
Databáze: Supplemental Index