Direct 13C-13C spin-spin coupling constants in the vinyl group of N-vinylazoles

Autor: Afonin, A. V., Krivdin, L. B., Danovich, D. K., Voronov, V. K., Es'kova, L. A., Trzhtsinskaya, B. V., Baikalova, L. V., Buzilova, S. R., Gareev, G. A.
Zdroj: Chemistry of Heterocyclic Compounds; February 1989, Vol. 25 Issue: 2 p157-160, 4p
Abstrakt: The unshared electron pair of the dicoordinated nitrogen atom introduces a stereospecific contribution to the 13C-13C spin-spin coupling constant (SSCC) in the vinyl group of a series of N-vinylazoles, the value of which depends on the energetics of the unshared pair.
Databáze: Supplemental Index