Characteristics of heterocyclization of triketones of the 2-(3-oxopropyl)cyclohexane-1,3-dione series with hydroxylamine hydrochloride

Autor: Markova, L. I., Kazarinova, T. D., Yudovich, L. M., Karchenko, V. G.
Zdroj: Chemistry of Heterocyclic Compounds; February 1990, Vol. 26 Issue: 2 p178-183, 6p
Abstrakt: A rearrangement that leads to the formation of mixtures of 2,4- and 2,3-diaryl-substituted 5-oxotetrahydroquinoline oximes was observed in the heterocyclization of oxo 1,5-diketones of the 2-(3-oxopropyl)cyclohexane-1,3-dione series, as well as in the recyclization of 5-oxotetrahydro-4H-chromenes, in the presence of excess hydroxylamine hydrochloride. It was established that the rearrangement proceeds only when electron-donor groups are present in the starting compounds.
Databáze: Supplemental Index