Reactions of heterocyclic cations with n-containing nucleophiles. 15. Reaction of 2,6-diphenylpyrylium perchlorate with semi- and thiosemicarbazides

Autor: Zvezdina, é. A., Zhdanova, M. P., Anisimova, O. S., Nechayuk, I. I.
Zdroj: Chemistry of Heterocyclic Compounds; December 1986, Vol. 22 Issue: 12 p1322-1326, 5p
Abstrakt: The reaction of 2,6-diphenylpyrylium perchlorate with semi- and thiosemicarbazides in ethanol leads to 1-carbamoyl- and 1-thiocarbamoyl-3-phenyl-5-phenacyl-4,5-dihydropyrazoles, the cyclization of which yields 2,5-diphenyl-7-oxo(thio)-pyrazolo[1,5-c]pyrimidines. The tautomeric form of the latter is established by comparing their electronic absorption spectra with the spectra of the methyl derivatives.
Databáze: Supplemental Index