Reduction of enamines of the 3,3-dialkyl-3,4-dihydroisoquinoline series

Autor: Gavrilov, M. S., Shklyaev, V. S., Aleksandrov, B. B.
Zdroj: Chemistry of Heterocyclic Compounds; August 1987, Vol. 23 Issue: 8 p871-874, 4p
Abstrakt: Lithium aluminum hydride reduced enamines of the 3,3-dialkyl-3,4-dihydroisoquinoline series to the corresponding tetrahydroisoquinolines. In the presence of a hydrogen atom at the ?-carbon atom of the enamino ester the action of lithium aluminum hydride and alkylmagnesium bromide leads to the products from the condensation of two molecules of the initial compound.
Databáze: Supplemental Index