Formation of 1,4- and 1,5-regioisomers of triazolines in reactions of 2-ethoxyethyl azide with monosubstituted ethylenes

Autor: Lanovaya, G. A., Mishchenko, V. F., Korniets, E. D.
Zdroj: Chemistry of Heterocyclic Compounds; June 1987, Vol. 23 Issue: 6 p660-664, 5p
Abstrakt: The structural specificity of the reactions of 2-ethoxyethyl azide with alkenes RCH=CH2 [R=CH2C6H5, CH2OC6H13, CH(OC2H5)2, C6H5] was studied. The formation of 1,4- and 1,5-substituted triazolines and the high stabilities of the latter were demonstrated by PMR spectroscopy, data from gas-liquid chromatography (GLC), and the kinetics of thermolysis.
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