Heterogyclization of triketones of the 2-(3-oxopropyl)-cyclohexane-1,3-dione series

Autor: Kharchenko, V. G., Markova, L. I., Kazarinova, T. D., Yudovich, L. M.
Zdroj: Chemistry of Heterocyclic Compounds; July 1985, Vol. 21 Issue: 7 p758-761, 4p
Abstrakt: Triketones of the 2-(3-oxopropyl) cyclohexane-1,3-dione series have been shown for the first time to react with boron trifluoride etherate to give the novel 5-oxo-5,6,7,8-tetrahydrochromylium fluoroborates, which in turn react with ammonia to give 5-oxo-5,6,7,8-tetrahydroquinolines. These were also obtained directly from ammonium acetate and 2-(3-oxopropyl)cyclohexane-1,3-diones.
Databáze: Supplemental Index