Research on 1, 2, 4-triazoles
| Autor: | Postovskii, I. Ya., Shegal, I. L. |
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| Zdroj: | Chemistry of Heterocyclic Compounds; May 1966, Vol. 1 Issue: 3 p296-299, 4p |
| Abstrakt: | Cyanoethylation of 4-aryl-1, 2, 4-triazolinethiones-3 takes place at the nitrogen atom of the thioamide group, to give N-cyanoethyl derivatives. ß-Chloropropionitrile reacts at the nitrogen atom of the thioamide groups, but ß-chloropropionic acid reacts at its sulfur atom, giving a sulfide. The results of cyanoethylation enable conclusions to be drawn regarding the shift of the reaction center from sulfur to nitrogen on passing from a tetrazole to a triazole derivative. |
| Databáze: | Supplemental Index |
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