Synthesis of bis(o-hydroxyphenyl)-1,3,5-triazines, 1,2,4-triazoles, and oxadiazole by recyclization of the o-hydroxyphenyl-4-oxo-1,3-benzoxazinium cation

Autor: Ryabukhin, Yu. I., Faleeva, L. N., Korobkova, V. G.
Zdroj: Chemistry of Heterocyclic Compounds; March 1983, Vol. 19 Issue: 3 p332-336, 5p
Abstrakt: The acidic cyclization of disalicylamide gave 2-(o-hydroxyphenyl)- and 2-(o-acetoxyphenyl)-4-oxo-1,3-benzoxazinium perchlorates, by reaction of which with hydroxylamine, hydrazines, benzamidine, guanidines, and S-methylisothiourea bis(o-hydroxyphenyl)-1,2,4-oxadiazole, triazoles, and sym-triazines were synthesized. Mono- and bis (o-acetoxyphenyl) triazoles were obtained.
Databáze: Supplemental Index