| Autor: |
Litvinenko, G. S., Khludneva, K. I., Krasnomolova, L. P. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; November 1983, Vol. 19 Issue: 11 p1210-1212, 3p |
| Abstrakt: |
The stepwise protonation of amines can be utilized for the interpretation of the PMR spectra of conjugated pairs consisting of an amine and its salt. A linear dependence of the proton chemical shifts on the composition of the amine-salt system has been demonstrated in the example of 2a-methyl-4-keto-trans-decahydroquinoline, making it possible to determine the proton chemical shifts, which are hidden in one of the partners by other signals, by means of extrapolation. The chemical shifts of the protons nearest the nitrogen atom vary in the following order upon protonation: a-Hatert> a-Heetert˜ ß-Hatert> ß-Hasec˜ ß-Hesec˜ ß-Hpr. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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