Mass spectrometry of biologically active substances

Autor: Voronin, V. G., Ermakov, A. I., Paramonov, N. K., Portnov, Yu. N., Goncharenko, S. B.
Zdroj: Chemistry of Heterocyclic Compounds; June 1978, Vol. 14 Issue: 6 p667-671, 5p
Abstrakt: The mass spectra of 2- and 4-iminobarbituric acid derivatives were studied in relation to the mass spectra of their oxygen analogs. It is shown that the pathways of fragmentation of the investigated compounds depend on the type of substituent attached to the C5 atom, the position of the imino and oxo groups in the ring, and the specific mass-spectral properties. The fragmentation was studied by means of low-voltage mass spectrometry and deuterium labeling.
Databáze: Supplemental Index