Synthesis of dimethylamino derivatives of some condensed heterocycles from dimethylphosgeneimmonium chloride

Autor: Gorelik, M. V., Kuleshova, N. D., Arinich, L. V.
Zdroj: Chemistry of Heterocyclic Compounds; March 1978, Vol. 14 Issue: 3 p332-335, 4p
Abstrakt: Diazo coupling of indazole-3-diazonium chloride with 1-(2,4-dinitrophenyl)-3,5-bis(dimethylamino)pyrazole, obtained from dimethylphosgeneimmonium chloride, and subsequent cyclization of the azo compound lead to the formation of the dimethylamino derivatives of a new polycyclic system — benzo[h]dipyrazolo[3,2-c:3',4'-e]-1,2,4-triazine. Previously unknown 3-dimethylamino derivatives of 1,2,4-triazolo-[3,4-b]benzothiazole were synthesized by reaction of dimethylphosgeneimmonium chloride with 2-hydrazinobenzothiazoles.
Databáze: Supplemental Index