Stereochemistry of the 1,4-redugtion of chiral N-(α-phenylethyl)-Δ9,10-4-ketooctahydroquinoline
Autor: | Potapov, V. M., Grishina, G. V., Golov, E. A., Terent'ev, P. B., Khertsshu, R. |
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Zdroj: | Chemistry of Heterocyclic Compounds; July 1976, Vol. 12 Issue: 7 p790-793, 4p |
Abstrakt: | Only trans-N-(α-phenylethyl)-4-ketodecahydroquinoline, which is readily converted to a mixture containing 70% of the thermodynamically more stable cis isomer, is formed in the reduction of chiral N-(α-phenylethyl)-Δ9,10-4-ketooctahydroquinoline with lithium aluminum hydride. |
Databáze: | Supplemental Index |
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