Stereochemistry of the 1,4-redugtion of chiral N-(α-phenylethyl)-Δ9,10-4-ketooctahydroquinoline

Autor: Potapov, V. M., Grishina, G. V., Golov, E. A., Terent'ev, P. B., Khertsshu, R.
Zdroj: Chemistry of Heterocyclic Compounds; July 1976, Vol. 12 Issue: 7 p790-793, 4p
Abstrakt: Only trans-N-(α-phenylethyl)-4-ketodecahydroquinoline, which is readily converted to a mixture containing 70% of the thermodynamically more stable cis isomer, is formed in the reduction of chiral N-(α-phenylethyl)-Δ9,10-4-ketooctahydroquinoline with lithium aluminum hydride.
Databáze: Supplemental Index