Electrophilic substitution of acetamido- and acetoxybenzo-1,4-dioxanes

Autor: Daukshas, V. K., Purvanetskas, G. V., Balyavichyus, L. Z., Udrenaite, É. B., Gineitite, V. L.
Zdroj: Chemistry of Heterocyclic Compounds; April 1977, Vol. 13 Issue: 4 p373-378, 6p
Abstrakt: The products of acylation, bromination, and nitration of 5- and 6-acetamido- and 5- and 6-acetoxybenzo-1, 4-dioxanes were established. It is shown on the basis of calculations by the self-consistent field (SCF) MO LCAO method that the directions of the electrophilic substitution reactions of these derivatives and of benzo-1,4-dioxane correspond to the p-electron population of the AO of the carbon atoms of the aromatic ring stipulated by the boundary occupied MO.
Databáze: Supplemental Index