| Autor: |
Aslanov, L. A., Ionov, V. M., Andrianov, V. I., Safina, Z. Sh., Shashkov, A. Yu. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; December 1977, Vol. 13 Issue: 12 p1299-1303, 5p |
| Abstrakt: |
The crystal and molecular structures of 2,10-diacetoxy-13-thiabicyclo[7.3.1]-cis-tridec-5-ene and 2,9-dichloro-13-thiablcyclo[8.2.1]-cis-tridec-5-ene sulfoxide were established. The conformations of the molecules are such that the unshared pairs of electrons of the sulfur atoms are directed to the carboncarbon double bonds of their molecules. It was observed that there are stereochemical conditions for transannular transformations under the influence of polarized molecules and cations. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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