Autor: |
Loseva, N. S., Nivorozhkin, L. E., Borisenko, N. I., Minkin, V. I. |
Zdroj: |
Chemistry of Heterocyclic Compounds; November 1974, Vol. 10 Issue: 11 p1305-1308, 4p |
Abstrakt: |
2,5-Dimethyl- and 2-ethyl-5-methyl-1,3-benzodithiolium perchlorates react with dimethylformamide and N-phenyl-N-methylaminoacrolein to give monoiminium salts, the hydrolysis of which yields the corresponding aldehydes. The trans-transoid structure ofß-formylvinyl-substituted 2-methylenebenzo-1,3-dithioles was established by a comparison of the experimental and calculated dipole moments, absorption maxima, and intensities of the electron transitions and also by analysis of the PMR spectra. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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