| Autor: |
Postovskii, I. Ya., Sinegibskaya, A. D., Kovalev, E. G. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; April 1975, Vol. 11 Issue: 4 p500-503, 4p |
| Abstrakt: |
The hydrazinolysis of 2-mercapto[1,2,4]triazolino[3,4-b][1,3,4]triadiazole-5-thione and its S-methyl and disulfonyl derivatives leads to opening of the thiadiazole ring during attack by the nucleophile on the bridge carbon atom. A study of the structures of the reaction products and calculations by the Hückel MO and Pariser-Parr-Pople (PPP) method makes it possible to draw a conclusion regarding the mechanism of the hydrazinolysis. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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