Synthesis and some properties of thiols, sulfides, and disulfides of the sulfolane series

Autor: Bezmenova, T. É., Varshavets, T. N., Matyash, L. T.
Zdroj: Chemistry of Heterocyclic Compounds; February 1975, Vol. 11 Issue: 2 p159-162, 4p
Abstrakt: Sulfolanethiols, which were oxidized to 3,3'-disulfolanyl disulfide and 3,3'-bis(4-hydroxysulfolanyl) disulfide, were obtained by reaction of 3-sulfolene and 4-hydroxy-2-sulfolene with sodium hydrosulfide. Previously unknown cleavage of the sulfolanyl sulfides at the C-S bond of the sulfolane ring was observed during their oxidative chlorination and alkaline hydrolysis.
Databáze: Supplemental Index