The martensitic transformation and the mechanical condition of phases

Autor: Blanter, M. E.
Zdroj: Metal Science and Heat Treatment; May 1975, Vol. 17 Issue: 5 p370-374, 5p
Abstrakt: 1.The cessation of the martensitic transformation in steel and the resumption of the transformation at lower temperatures depend on the change in the mechanical condition of the original phase (austenite) with a simultaneous change in the value of the thermodynamic stimulus of the transformation \3- the difference in free energies \gDFAM. The equation of the martensite curve (9) was derived from comparison of the temperature dependence of \gDFAMT with the resistance of austenite to transformation s0.2TThe equation obtained indicates that with a constant thermodynamic factor (T0) the values of MS and Mf and the rate of the transformation depend on the original mechanical condition of austenite and its capacity for increasing in strength due to phase strain hardening in the process of the transformation.2.The condition for complete suppression of the martensitic transformation was shown for any cooling conditions by means of increasing the strength of austenite in macrovolumes and for whiskers.3.A martensite diagram for iron-carbon alloys was constructed by means of calculations. The calculated curve for TMS is in good agreement with the experimental data. The calculated curve for TMS differs substantially from the experimental data for alloys with over 1% C.4.The thermodynamic conditions for nucleation of martensite crystals can be utilized only in the case where they are sufficient to overcome the mechanical resistance of the original phase to the transformation. This resistance depends on the original mechanical condition of austenite and its variation with phase strain hardening in the process of the martensitic transformation.
Databáze: Supplemental Index