On the energy transfer at the radiolysis of CO-H2S gas mixture

Autor:	Kurbanov, M., Mamedov, Kh., Iskenderova, Z.
Zdroj:	Journal of Radioanalytical and Nuclear Chemistry; October 1988, Vol. 128 Issue: 3 p195-200, 6p
Abstrakt:	Abstract: The kinetics of hydrogen formation at various amounts of H2S /1–60%/ in the radiolysis of CO–H2S mixture has been studied. The ratio of the reaction rate constants for reactions COx+COrarrproduct and COx+H2SrarrH+SH=CO, which amounts to sim5×10–2, has been estimated. The effective activation energy of hydrogen formation /Eeff/ has been determined at various amounts of H2S in the temperature interval 323–573 K.
Databáze:	Supplemental Index
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