The structure of the sesquiterpene lactone repin

Autor: Evstratova, R., Rybalko, K., Sheichenko, V.
Zdroj: Chemistry of Natural Compounds; July 1972, Vol. 8 Issue: 4 p450-457, 8p
Abstrakt: 1. Three sesquiterpene lactones have been isolated fromCentaurea hyrcanica: repin, acroptilin, and a new lactone related to them with mp 218–220°C (ethanol), [α]D20+ 104.7° (c 1.91; dioxane). 2. Structure (I) has been proposed for repin on the basis of the reactions performed, of an interpretation of the NMR spectra of compounds (I-XII) using the INDOR method, and also of a study of NMR spectra with additions of a paramagnetic salt.
Databáze: Supplemental Index