Thermal decompositions of silver carboxylates

Autor: Burleva, L., Andreev, V., Boldyrev, V.
Zdroj: Journal of Thermal Analysis and Calorimetry; September 1988, Vol. 33 Issue: 3 p735-739, 5p
Abstrakt: The thermal decompositions of the even silver dicarboxylates from silver oxalate to silver sebacate were studied. In vacuum, the dicarboxylates decomposed to give metallic silver, CO2 and organic diradicals as primary products, and polymers as secondary products. The higher silver dicarboxylates were much more stable to thermal treatment than silver oxalate, probably due to the initiation of decomposition of all carboxylates except silver oxalate by the rupture of a Ag-O and not a C-C bond.
Databáze: Supplemental Index