Siliconizing as a method for the production of acid-resistant modifications of faujasite

Autor: Bobonich, F. M., Voloshina, Yu. G., Solomakha, V. N.
Zdroj: Theoretical and Experimental Chemistry; January 1996, Vol. 32 Issue: 1 p47-50, 4p
Abstrakt: It was shown that acid-resistant modifications of faujasite can be produced by its thermal treatment in silicon tetrafluoride vapor if the ratio of the atoms in the zeolite framework is increased as a result of such treatment to Si/Al = 12. At lower degrees of isomorphous substitution of the atoms. the faujasite crystal lattice is destroyed in a 5 M solution of hydrochloric acid as a result of the low acid resistance of the aluminum-oxygen tetrahedra of the zeolite and of the imperfections in its structure.
Databáze: Supplemental Index