| Autor: |
Popov, E. M., Kogan, G. A., Zheltova, V. N. |
| Zdroj: |
Theoretical and Experimental Chemistry; January 1972, Vol. 6 Issue: 1 p11-19, 9p |
| Abstrakt: |
The “bond order—bond length”, “bond length—average percentage s-character”, and “bond order—bond p-shortening” relationships have been obtained for CN and CO bonds. It has been shown that the differences in bond lengths are due chiefly to the specific features of the s-bonds. The observed relationship between the length of the s-bond and the average percentage s-character is linear. It has been noted that the bond lengths are most sensitive to the p-order when it changes in the range 0.3–1.0. For CC, CN, and CO bonds, relationships have been obtained between the p-order and the force constants, and for the single bonds the relationship between the average percentage s-character and the force constants has been obtained. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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