| Autor: |
Smirnov, M. V., Khaimenov, A. P. |
| Zdroj: |
Theoretical and Experimental Chemistry; January 1970, Vol. 4 Issue: 1 p40-44, 5p |
| Abstrakt: |
Starting from our previously proposed model of fused alkali metal halides, we discuss the processes involved in the mixing of fused alkali metal halides and dissolution (mixing) of TiCl4(g)[ZrCl4(liq)] in fused alkali metal halides and their mixtures. The resulting quantities are compared with the experimental. They vary with changes in the radius of the salt-solvent cation in the same direction as the experimental values. The dissolution of KClz in mixtures of fused alkali metal halides was considered from the point of view of the energy nonuniformity of the Me1+ and Me2+ cations. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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