Formation of the active component of a vanadium-molybdenum oxide catalyst in acrolein oxidation

Autor: Kuznetsova, T. G., Boreskov, G. K., Andrushkevich, T. V., Plyasova, L. M., Maksimov, N. G., Olenkova, I. P.
Zdroj: Reaction Kinetics and Catalysis Letters; December 1979, Vol. 12 Issue: 4 p531-536, 6p
Abstrakt: An acrolein-containing reaction mixture reduces V5+ to V4+, accompanied by decomposition of the ammonium salt of vanadium-molybdenum-silicon heteropolyacid (HPA) to form a compound with the tentative composition of VMo3O11+x, which is the active component of the catalyst.
Databáze: Supplemental Index