| Autor: |
Zeif, A. P., Sokolovskii, V. D., Vadash, P. I. |
| Zdroj: |
Reaction Kinetics and Catalysis Letters; January 1979, Vol. 10 Issue: 1 p71-75, 5p |
| Abstrakt: |
The interaction of propylene with gallium oxide has been studied by the MINDO-3 method using a cluster model. It is shown that the energy barrier against allyl C−H bond dissociation is mainly determined by the Coulomb repulsion between the molecule and the central metal ion. Interaction of the dissociating hydrogen with the oxygen of the fragment ensures the stabilization of the system. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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