Homo- and copolymerization of some norbornadiene dimer monomers

Autor: Alonso, Maria A., Farona, Michael F.
Zdroj: Polymer Bulletin; September 1987, Vol. 18 Issue: 3 p203-207, 5p
Abstrakt: The exo-exo and endo-endo norbornadiene dimers were synthesized and homopolymerized using the Re(CO)5Cl/EtAlCl2 catalyst system. The exo-exo dimer was copolymerized with norbornene, both as a random polymer and as a diblock. In all cases, the polymers obtained were mainly of the ring-retained, rather than ring-opened type, even though Re(CO)5Cl/EtAlCl2 is an olefin metathesis catalyst and the monomers are strained ring systems.
Databáze: Supplemental Index