| Autor: |
Perumareddi, Jayarama R., Collins, John A. |
| Zdroj: |
Theoretica Chimica Acta; December 1980, Vol. 54 Issue: 4 p315-321, 7p |
| Abstrakt: |
In the presence of spin-orbit interaction, in addition to the well-known weak-field coupling scheme for cubic complexes in which the ligand field perturbation is applied last, we show that it is possible to devise a second weak-field coupling scheme in which the spin-orbit perturbation is applied last by constructing the corresponding energy matrices for d2,8 electronic configurations. We also show that for the parameters applicable to actual experimental systems, the new weak-field coupling scheme yields purer eigenfunctions than the well-known weak-field coupling scheme. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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