Biocatalytic synthesis of (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, aggregation pheromone components ofDrosophila mulleri andD. busckii, by enantioselective hydrolysis with lipase

Autor: Kamezawa, Makoto, Tachibana, Hojun, Ohtani, Takehiko, Naoshima, Yoshinobu
Zdroj: Journal of Chemical Ecology; May 1994, Vol. 20 Issue: 5 p1057-1061, 5p
Abstrakt: The two chiral pheromone acetates, (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, were synthesized with an enantiomeric excess (e.e.) of almost 100% byPseudomonas cepacia lipase-catalyzed hydrolysis of their corresponding racemic acetates in an acetone-water solvent system.
Databáze: Supplemental Index