Biocatalytic synthesis of (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, aggregation pheromone components ofDrosophila mulleri andD. busckii, by enantioselective hydrolysis with lipase
Autor: | Kamezawa, Makoto, Tachibana, Hojun, Ohtani, Takehiko, Naoshima, Yoshinobu |
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Zdroj: | Journal of Chemical Ecology; May 1994, Vol. 20 Issue: 5 p1057-1061, 5p |
Abstrakt: | The two chiral pheromone acetates, (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, were synthesized with an enantiomeric excess (e.e.) of almost 100% byPseudomonas cepacia lipase-catalyzed hydrolysis of their corresponding racemic acetates in an acetone-water solvent system. |
Databáze: | Supplemental Index |
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